|
|
tert-butoxymethanol + NAD+ <=> tert-butyl_formate + NADH + H+
|
1.1.1.M26
|
–
|
|
MetaCyc:
RXN-17613
|
|
|
|
ATP + 2-Methyllactate + CoA <=> 2-hydroxy-2-methylpropanoyl-CoA + AMP + diphosphate
|
6.2.1.M4
|
–
|
|
MetaCyc:
RXN-17606
|
|
|
|
tert-butanol + O2 + NADPH + H+ <=> isobutane-1,2-diol + NADP+ + H2O
|
1.14.13.229
tert-butyl alcohol monooxygenase
|
–
|
|
BRENDA:
BR51804
KEGG:
R11447
MetaCyc:
RXN-17610
|
|
|
|
methyl_tert-butyl_ether + O2 + NADH + H+ <=> tert-butoxymethanol + H2O + NAD+
|
1.14.13.M36
|
–
|
|
MetaCyc:
RXN-17612
|
|
|
|
tert-butyl_formate + H2O <=> tert-butanol + formate + H+
|
3.7.1
|
–
|
|
MetaCyc:
RXN-17615
|
|
|
|
2-hydroxy-2-methylpropanoyl-CoA <=> (S)-3-hydroxybutyryl-CoA
|
5.4.99.64
2-hydroxyisobutanoyl-CoA mutase
|
–
|
|
BRENDA:
BR51727
KEGG:
R11334
MetaCyc:
RXN-17605
|
|
|
|
(S)-3-hydroxybutyryl-CoA + NAD+ <=> acetoacetyl-CoA + NADH + H+
|
1.1.1.178
3-hydroxy-2-methylbutyryl-CoA dehydrogenase
1.1.1.35
3-hydroxyacyl-CoA dehydrogenase
1.1.1.36
acetoacetyl-CoA reductase
|
–
–
–
|
|
BRENDA:
BS188053
KEGG:
R01975
MetaCyc:
RXN-11662
SABIO-RK:
2018
|
|
|
|
2-hydroxy-2-methylpropanal + NAD+ + H2O <=> 2-Methyllactate + NADH + H+
|
1.2.1.98
2-hydroxy-2-methylpropanal dehydrogenase
|
–
|
|
BRENDA:
BR51647
KEGG:
R11350
MetaCyc:
RXN-17603
|
|
|
|
isobutane-1,2-diol + NAD+ <=> 2-hydroxy-2-methylpropanal + NADH + H+
|
1.1.1.400
2-methyl-1,2-propanediol dehydrogenase
|
–
|
|
BRENDA:
BR51642
KEGG:
R11338
MetaCyc:
RXN-17602
|
|
|
|
acetyl-CoA <=> acetoacetyl-CoA + CoA
|
1.1.1.34
hydroxymethylglutaryl-CoA reductase (NADPH)
2.3.1.155
acetyl-CoA C-myristoyltransferase
2.3.1.16
acetyl-CoA C-acyltransferase
2.3.1.38
[acyl-carrier-protein] S-acetyltransferase
2.3.1.9
acetyl-CoA C-acetyltransferase
|
–
–
–
–
–
|
|
BRENDA:
BR44092
KEGG:
R00238
MetaCyc:
ACETYL-COA-ACETYLTRANSFER-RXN
SABIO-RK:
531
|
|